The Springboks, as expected, made a raft of changes to the matchday 23.
The two players joined the side in August for training and will play for Maccabi FC in the new season.
Having been mocked in the verbal sparring before the Test as the 'Old Blacks' and 'over the hill', the All Blacks dug deep into their wealth of experience to outscore the Wallabies five tries to nil.
Cyle Brink has recovered from a broken wrist and has also been included on the bench.
Thabo Qalinge had been training with the Pretoria-based side since the start of July after being released by Pirates in June.
Djokovic was never in danger in his 6-3, 6-4 triumph over 53rd-ranked Spaniard Pablo Carreno Busta, whom he finished off in 90 minutes.
While the South Africans are on the rise and looking increasingly like contenders to win the global championship a record-equalling third time, the Argentines are in the doldrums.
The tournament starts on Saturday, with defending champions Cape Town City FC in action against Polokwane City at Newlands Stadium, Cape Town.
Nkwe replaces West Indian Ottis Gibson, the previous head coach, for the trip which starts in September and includes three Tests and three Twenty20 Internationals.
There is no doubting the 27-year-old forward is a brilliant player, and there is every chance he will get the success he craves by returning to Spain, whether with his old club or Real Madrid.
